Fabrication of in-situ Ti-Cx-N1−x phase enhanced porous Si3N4 absorbing composites by gel casting
In view of the lack of a conformal, load-bearing, lightweight, and high-temperature resistant integrated microwave-absorbing composites for applications under extremely complex conditions, this study successfully applies gel casting craft to porous Si 3 N 4 microwave-absorbing composites. The high-temperature decomposition reaction of Ti 3 SiC 2 powder was utilized to generate uniform Ti-C x -N 1−x grains in situ and to enhance the mechanical and microwave-absorption properties of porous Ti-C x -N 1−x /Si 3 N 4 composites. The bending strength , fracture toughness, density, maximum reflection loss value, absorption bandwidth and matched thickness in P-band of the composite with 30 wt% Ti 3 SiC 2 addition were 164.87 ± 7.56 MPa, 2.61 ± 0.13 MPa·m 1/2 , 2.077 g/cm 3 , 32.42 dB, 1.74 GHz and 4.2 mm, respectively. The fracture toughness and bending strength of the composite were increased by 71.71% and 58.13%, respectively, compared with monolithic porous Si 3 N 4 . The electromagnetic wave loss mechanisms of the composites are proposed as a combination of conductivity loss, multiple reflections and scattering, interfacial polarization and defect polarization.
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