VACUUM
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2022
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IF 4.11
Jingyun Chun,Xiaolong Wang,Yuchan Zhang,Chuanliang Wei,Zhengran Wang,Jinkui Feng
Sodium-ion batteries (SIBs) are ideal technologies for large-scale energy storage systems because of their abundant resources and low cost. However, Al foil, the current collector of sodium-ion battery, has a great influence on the performance of the battery, but it has rarely been studied. In this paper, we prove that the Ti 3 C 2 T x MXene current collector can make a stronger connection with the electrode, lowering the electrode-collector interface resistance considerably. When compared to Al current collectors in SIBs, the Ti 3 C 2 T x MXene current collector reduces polarization and enhances performance. the sodium vanadium phosphate(NVP) electrode with Ti 3 C 2 T x MXene current collector exhibits significantly enhanced rate capability (81.9 mAh g −1 at 500 mA g −1 ) and cycling performance (81.5% over 200 cycles at 1C) than Al foil. The results show that Ti 3 C 2 T x MXene current collector has a broad prospect in the application of high power SIB battery.
研究领域:
材料科学
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能源存储技术
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF COLLOID AND INTERFACE SCIENCE
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2021
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IF 8.128
Handan Liu,Yanyan Liu,Dan Xu,Long Chen,Wen Guo,Tiantian Gu,Feng Yu,Gang Wang
Ti 3 C 2 T x , a member of the MXene, has attracted extensive interest because of its high conductivity, unique two-dimensional (2D) structure and intrinsic pseudocapacitance for supercapacitors. Flexible and freestanding Ti 3 C 2 T x films are promising electrodes for functioned supercapacitors used in wearable and portable electronic devices. However, the severe self-restacking of 2D Ti 3 C 2 T x nanosheets restraints their practical application. Herein, freestanding and flexible three-dimensional (3D) cross-linked Ti 3 C 2 T x -Ca-SA (sodium alginate) films with expanded Ti 3 C 2 T x interlayer spacing are reported. The expanded interlayer spacing allows more electrolyte ions to quickly intercalate providing more intercalation pseudocapacitance, while the 3D cross-linked microstructure ensures a continuous conductive network facilitating charges transport. Attributing to the unique structure, the Ti 3 C 2 T x -Ca-SA film delivers an outstanding areal capacitance (633 mF cm −2 at 5 mV s −1 ). Meanwhile, the assembled all-solid-state pseudocapacitor shows good flexibility and capacity stability under various bending conditions. The device exhibits a high energy density up to 12.6 µWh cm −2 at the power density of 375 µW cm −2 and excellent cycling stability, which are much better than prior reported state-of-the-art supercapacitors. This research exploits a simple method to optimize the structure of MXene as state-of-the-art electrodes for high-performance flexible energy-storage devices.
研究领域:
材料科学
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能源存储
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纳米技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
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2023
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IF 4.5
Yong Liu,Xudong Liu,Shangli Dong,Xuefeng Zhang,Yidan Wei,Lu Lv,Sirui He
The closely restacked MXene nanosheets obstruct electrolyte ion transfer in electrodes, limmiting the electrochemical performance at a high charging-discharging rate. Although various 3D porous structures have been constructed, size effect of porous MXenes electrodes has been rarely studied. Herein, the classical metal ion-assisted method was used to fabricate 3D porous MXene films. The pore size distribution was changed by adjusting the cation valency. Noteworthy, when the mesoporous pore size distribution is in the range of 5 ∼ 10 nm, the porous structure can significantly improve the electrochemical performance and the presence of micropores can increase the proportion of surface capacitance. As a result, the porous Ti 3 C 2 T x film treated by Mg 2+ showed outstanding electrochemical performance, with both high capacity (420F/g at 2 mV/s) and good cyclic stability (94.4% retention after 5000 cycles). This work presents a study on how pore size distribution of porous MXene film effects the electrochemical performance and provides a reference for the design of 3D porous MXene electrodes.
研究领域:
材料科学
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电化学
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储能技术
✓ 已验证
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
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2021
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IF 13.273
Zongxu Liu,Wenyan Wang,Jin Liu,Baolei Zhu,Guoxian Zhang,Jinxin Wang,Hepeng Zhang,Qiuyu Zhang
Nacre-mimetic strategy provides an enlightening approach to design high-performance bioinspired nanocomposites. Yet, it is still a big challenge to integrate excellent mechanical properties and tunable multifunctionality into artificial nacre materials. Herein, we develop a pioneering strategy to simultaneously modulate the electrical conductivity and mechanical properties of nacre-mimetic nanocomposite films by controlling interlay supramolecular interactions. A series of novel waterborne polyurethanes with 2-ureido-4[1H]-pyrimidinone (UPy) quadruple hydrogen bonding motifs in the side-chains were elaborately designed and synthesized, and further assembled with Ti 3 C 2 T x MXene nanosheets to construct lamellar nacre-mimetic nanocomposite films with highly ordered nanostructure. This research revealed for the first time that merely varying the content of UPy groups on polyurethane realize significant modulation of mechanical properties, electrical conductivity, and even the electromagnetic shielding effectiveness of nacre-mimetic nanocomposites. Strikingly, the tensile strength of the nanocomposites can be improved from 87.91 to 136.96 MPa and the electrical conductivity from 3214.0 to 4136.1 S cm −1 when the UPy content is increased from 0 to 15%. Additionally, the nacre-mimetic nanocomposite film is capable of fast responsive Joule heating performance at low trigger voltage. This work would open up a new avenue for fabricating multifunctional and mechanically robust biomimetic nanocomposites.
研究领域:
材料科学
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纳米技术
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复合材料
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仿生学
✓ 已验证
产品关联
DOI
高影响因子
Nano Research
·
2023
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IF 9.9
Xi Guangshuai,Zhang Dongzhi,Tang Mingcong,Zhang Hao,Sun Yuehang,Zhang Yubiao,Cai Haolin,Xia Hui,Zhou Dandi
In recent years, multi-modal flexible tactile sensors have become an important direction in the development of electronic skin because of their excellent sensitivity, flexibility and wearable properties. In this work, a humidity-pressure multi-modal flexible sensor based on polypyrrole (PPy)/Ti 3 C 2 T x sensitive film packaged with porous polydimethylsiloxane (PDMS) is investigated by combining the sensitive structure generation mechanism of in situ polymerization to achieve the simultaneous detection of humidity and pressure, which has a sensitivity of 89,113.4 Ω/% RH in a large humidity range of 0%–97% RH, and response/recovery time of 2.5/1.9 s. The tactile pressure sensing has a high sensitivity, a fast response of 67/52 ms, and a wide detection limit. The device also has excellent performance in terms of stability and repeatability, making it promising for respiratory pattern and motion detection. This work provides a new solution to address the construction of multi-modal tactile sensors with potential applications in the fields of medical health, epidemic prevention.
研究领域:
电子皮肤
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传感器
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可穿戴技术
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医疗健康
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疫情防控
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）