One-dimensional Z-scheme TiO 2 /WO 3 /Pt heterostructures were fabricated by integrating a facile electrospinning technique and subsequent annealing in air. X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and UV–vis diffuse reflectance spectroscopy, were used to characterize the as-fabricated samples. The results showed that the H 2 -generation of the as-fabricated one-dimensional Z-scheme TiO 2 /WO 3 /Pt heterostructures (S2) was greatly enhanced compared with pure TiO 2 nanofibers (S0) and TiO 2 /WO 3 nanofibers (S1). The enhanced photocatalyst activities were mainly attributed to the solid-state Z-scheme photosynthetic heterojunction system with Pt nanoparticle as an electron collector and WO 3 as a hole collector, leading to effective charge separation on these semiconductors, which were evidenced by electrochemical impedance spectroscopy (EIS) and photocurrent analysis.
Han Zheng,Changhua Wang,Xintong Zhang,Lina Kong,Yingying Li,Yunyu Liu,Yichun Liu
Multi-heterojunctions are more promising than single-heterojunctions in photocatalysis due to the availability of more interfaces between each component. However, photocatalytic activity is highly dependent on the contact mode of individual components. In this work, we assemble TiO2–WO3–Pt multi-heterojunction microspheres using ultrasonic spray pyrolysis and focus on their contact mode governed photocatalytic activity. The results reveal that using highly crystalline WO3 nanosheets as building blocks could particularly enhance the photocatalytic activity of a TiO2/WO3 system toward the degradation of gaseous acetaldehyde and isopropyl alcohol. Furthermore, loading Pt nanoparticles onto WO3 nanosheets could facilitate a more prominent enhancement of activity than that of TiO2/Pt, benefiting from the two-electron reduction of oxygen at the interface of WO3/Pt. Meanwhile, the high crystallinity of WO3 nanosheets allows for a loading amount of Pt as low as 0.04 wt% in the TiO2–WO3–Pt system, which reduces the catalyst cost in comparison with that of the conventional amount of 1 wt%.
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