Electrospun Polymer Nanofibers with TiO2@NiCo-LDH as Efficient Polysulfide Barriers for Wide-Temperature-Range Li–S Batteries
Herein, we introduce polymer nanofibers of TiO2@NiCo-LDH as interlayers into Li–S batteries. From 0 to 60 °C, the interlayers can deliver high sulfur utilization, an outstanding rate capability, and excellent cycling life. High-temperature excitation makes it easier for the valence band electrons of TiO2 to transition to the conduction band. The electron–hole pairs formed on the surface combine with the ether group of 1,3-dioxolane in the electrolyte, which greatly reduces the decomposition and volatilization rates of the electrolyte, ensuring Li–S batteries with good cycle performance at high temperatures. The capacity can stabilize at 798.6 mAh g–1 after 100 cycles at 60 °C and 1C, and the battery can provide a capacity higher than 323.2 mAh g–1 at 0 °C. Simultaneously, the lithium metal symmetrical battery with a functional separator can be continuously cycled for 1800 and 750 h without a short circuit at the current densities of 0.65 and 1.63 mA cm–2, respectively.
危险品化学品经营许可证（带存储）