Highly adhesive and impact-strengthening supramolecular polyurethane derived from facile incorporation of UPy motifs toward energy dissipation binding applications
The implementation of hot melt adhesives reaching structural adhesion with both impact resistance and detachability is of prospective industry value but still remains challenging. In this work, 2-amino-4-hydroxy-6-methylpyrimidine serving as both chain extender and end-capping reagent due to its isomerism, was developed to construct a supramolecular polyurethane-derived hot melt structural adhesive. The as-synthesized PUM elastomers occurs obvious decrease of molecular weight at 80°C compared to room temperature, revealing the existence of self-complementary 2-ureido-4[1H]-pyrimidinone (UPy) motifs at chain ends. This unique structure allows to chemically incorporate abundant hierarchical and quadruple hydrogen bonding moieties, which results in remarkable enhancement of shear strength, ranging from 6.4 to 16.6 MPa. More importantly, it also exhibits unique impact-strengthening and reproducible adhering ability. The Hopkinson-press-bar and cyclic tensile tests manifest that quadruple hydrogen bonds play a pivotal role in buffering external forces and increasing energy dissipation when exposed to high velocity impacts. The true stress and strain synchronously increase as the strain rate augments while the shear strength can even roar up to ~18 MPa at high tensile speed. With regard to mild synthetic conditions, atomic economic use of reactants, it is promising that this material has industrial potential to be utilized in applications referred to energy-absorption and reproducible structural adhesion.
危险品化学品经营许可证（带存储）