Intelligent Off/On switchable electromagnetic wave absorbing material based on VO2 nanowires
With the development of modern communication devices, the demand for intelligent electromagnetic wave (EMW) absorbing materials that dynamically respond to environmental changes is ever-growing. However, the design and fabrication of high-performance EMW absorbing materials with adapt features remains challenging. Here, we report a temperature-responsive composite comprising VO 2 nanowires (NWs) and polyvinylidene fluoride-hexafluoropropylene copolymer (PVDF-HFP). Benefiting from the phase transition characteristics of VO 2 and the high aspect ratio of NWs, the composite demonstrates two distinct off/on switchable EMW absorbing performances as the temperature increases at low filler loading of VO 2 . The composite with 10 wt% VO 2 NWs transitions from transmission to absorption, showcasing a maximum change in reflection loss (RL) and effective absorption bandwidth (EAB) values of 53.09 dB and 4.85 GHz at the thin thickness of 2.5 mm and 2 mm, respectively. While the composite with 30 wt% VO 2 NWs shows a switch from absorption to reflection with the highest ΔEAB and ΔRL values of 3.59 GHz (1.5 mm) and 44.29 dB (2.5 mm), respectively. Additionally, radar cross-sectional (RCS) simulations verify the intelligent EMW absorbing performance of the composite. The work provides an effective and sustainable approach to harness the potential of VO 2 for developing tunable and high-performance wave-absorbing materials.
危险品化学品经营许可证（带存储）