查找使用阿拉丁产品的科研文献

VS4 nanoarrays pillared Ti3C2Tx with enlarged interlayer spacing as anode for advanced lithium/sodium ion battery and hybrid capacitor

Haoqiang Wang,Pengju Wang,Wei Gan,Lijie Ci,Deping Li,Qunhui Yuan

Aiming to improve the sluggish ion insertion/extraction at the battery-type anode in lithium-ion/sodium-ion hybrid capacitor (LIC/SIC), herein, a VS 4 @L-Ti 3 C 2 T x composing of VS 4 nanoarrays and MXene with enlarged interlayer spacing is developed through a facile hydrothermal approach. Benefiting from the merits of building blocks, the VS 4 @L-Ti 3 C 2 T x based lithium-ion half-cell exhibits superior specific capacity (1328 mAh g −1 after 170 cycles at 0.1 A g −1 ), rate performance (808 mAh g −1 after 10 cycles at 20 A g −1 ) and cycling stability (721 mAh g −1 after 500 cycles at 1.0 A g −1 ), surpassing most of the reported VS 4 based counterparts. The sodium-ion half-cell with VS 4 @L-Ti 3 C 2 T x anode also shows good performances. Moreover, LIC and SIC based on VS 4 @L-Ti 3 C 2 T x anodes deliver high energy densities of 122.5 Wh kg −1 and 117.0 Wh kg −1 at a low power density 100.3 W kg −1 , respectively. Additionally, they exhibit excellent cycling lifespans with capacity retention of 60% after 20000 cycles for LIC at a high current rate 1.0 A g −1 , outperforming most of the reported analogues. This study may shed light on the development of other layered anode materials for energy storage devices.