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In situ W/O Co-doped hollow carbon nitride tubular structures with enhanced visible-light-driven photocatalytic performance for hydrogen evolution

Haoshan Wei,Yong Zhang,Guoao Zhang,Jiewu Cui,Yan Wang,Yongqiang Qin,Xueru Zhang,Hark Hoe Tan,Jiaqin Liu,Yucheng Wu

Heteroatom co-doping has been considered as an effective strategy to simultaneously overcome intrinsic shortcomings of g-C 3 N 4 to achieve enhanced photocatalytic properties, in which the involved dopants could play its role in altering electronic structure, optical absorption and charge separation of the catalyst. Herein, W/O co-doped hollow g-C 3 N 4 tubular structures are successfully obtained for the first time via a one-step thermal decomposition. By W/O co-doping, architecture of g-C 3 N 4 is able to be modulated with enhanced optical absorption towards visible region. In addition, narrowed band gap and restrained charge recombination are conducive for the excitation of electron-hole pairs and transportation. Photocatalytic water splitting tests indicate that the co-doped hollow tubular g-C 3 N 4 structures enable superior activity for generating hydrogen up to 403.57 μmol g −1  h −1 driven by visible light, nearly 2.5 times as high as that of pristine g-C 3 N 4 . This work presents a rational strategy to design co-doped g-C 3 N 4 as an efficient visible-light-driven photocatalyst .