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WO3·0.5H2O
NEW JOURNAL OF CHEMISTRY · 2014 ·Vol. 38 ·期 7 ·3071-3077 · IF 3.159

Solvothermal synthesis of pyrochlore-type cubic tungsten trioxide hemihydrate and high photocatalytic activity

Yi Zheng,Gang Chen,Yaoguang Yu,Yu Wang,Jingxue Sun,Haiming Xu,Yansong Zhou

Pyrochlore-type cubic phase tungsten trioxide hemihydrate (c-WO3·0.5H2O) has been synthesized for the first time via a simple solvothermal process. The photocatalytic properties have been investigated firstly by the photodegradation of RhB, where the c-WO3·0.5H2O sample demonstrated high photocatalytic activity, indicating that c-WO3·0.5H2O is a promising candidate for tungsten oxide-based photocatalytic materials. The investigation result of the crystal water effects on the photocatalytic activity showed that crystal water of c-WO3·0.5H2O played a key role in the photocatalytic activity. The novel method reported in this study has great potential for the development of tungsten trioxide-based functional materials preparation, to improve their photocatalytic efficiency in the elimination of hazardous substance applications as well as for energy materials.

研究领域: 材料科学 · 环境科学
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