Zirconia nanofibers-loaded reduced graphene oxide fabrication for specific electrochemical detection of methyl parathion
Yttrium-stabilized zirconia@reduced graphene oxide (YSZ@rGO) nanofibers with uniform porous structure were prepared by electrospinning and thermal reduction process. On this basis, PEDOT/YSZ@rGO electrode was fabricated via the electrodeposition for sensitive detection of methyl parathion (MP). Among this, YSZ exhibited outstanding adsorption, rGO improved electron mobility and PEDOT enhanced electrocatalytic properties. The electrochemical impedance spectroscopy (EIS), square wave voltammetry (SWV) and cyclic voltammetry (CV) demonstrated the successful preparation of the sensor. The pH value of the buffer, the pre-deposition time of the working electrode, and the adsorption time have been optimized. Under the optimum condition, the detection limit of the sensor is 1.57 ng·mL −1 (S/N = 3), and the linear detection ranges from 5 to 4000 ng·mL −1 , which is superior to most related electrochemical sensors . Furthermore, the sensor exhibits good anti-interference, reproducibility, stability, and satisfactory recovery in real sample, indicating wide commercial applications in detecting food safety and monitoring wastewater emission.
危险品化学品经营许可证（带存储）