Fabrication, microstructure and properties of transparent Yb:Y2O3 ceramics from co-precipitated nanopowders
Ytterbium-doped yttrium oxide (5 at.%Yb:Y 2 O 3 ) nanopowders were synthesized by the co-precipitation method in this work. The influence of the molar ratio of ammonium hydrogen carbonate to metal ions (NH 4 HCO 3 /M 3+ , defined as R) on the properties of the precursors and powders was studied. The powders calcined at 1100 °C from the precursors with different R showed the same phase as the pure cubic Y 2 O 3 . However, the agglomerations of the calcined powders were influenced by the R evidently and the 5 at.%Yb:Y 2 O 3 powders with R = 4.0 showed better dispersivity. Using the obtained powders as starting materials, 5 at.%Yb:Y 2 O 3 transparent ceramics were fabricated by vacuum sintering and hot isostatic pressing (HIP) post-treating. The 5 at.%Yb:Y 2 O 3 ceramics with R = 4.0 possessed the best optical quality with the in-line transmittance of 81.2% at 1100 nm with fine grains. In addition, the microstructures of the 5 at.%Yb:Y 2 O 3 transparent ceramics with different R values were also studied and the HIP post-treated ceramics exhibited homogeneous microstructures. Meanwhile, the absorption and emission cross-sections of the 5 at.%Yb:Y 2 O 3 ceramics were calculated to be 0.99 × 10 −20 cm 2 at 976 nm and 0.97 × 10 −20 cm 2 at 1031 nm, respectively. The gain spectra also were obtained from the absorption and emission spectra.
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