Enhanced breakdown strength and restrained dielectric loss of polypropylene/maleic anhydride grafted polypropylene/core-shell ZrO2@SiO2 nanocomposites
To simoutinusly achieve improved breakdown strength (BDS) and suppressed dielectric loss, a modified ternary nanocomposite composed of polypropylene (PP), maleic anhydride-grafted PP and core-shell structure SiO 2 @ZrO 2 nanoparticles is proposed. By tailoring the thickness of SiO 2 shell from 3 to 11 nm and the nanofillers content from 0.5 to 5 wt%, the particles disparsion is improved and meanwhile both the deep trap density and the interaction force between molecules are enhanced. In consequence, the restricted transportation of electrons along molecule chains as well as between chains together raise the DC BDS, that the BDS of optimum sample film reaches 430.8 kV/mm, 23% higher than neat PP. Besides, the ternary nanocomposites with SiO 2 @ZrO 2 less than 3 wt% maintain the tanδ below 0.3% at a broad frequency ranging from 0.1 Hz to 100 kHz, which is an extremely low level same as neat PP.
危险品化学品经营许可证（带存储）