Thermal oxidation and compressive failure behavior of ZrSi2–B4C modified phenolic resin-based composite
Phenolic resin-based ablative materials have gained significant attention in the aerospace sector in recent years. In this study, TGA-DSC, FT-IR, XRD and XPS were employed to the thermal stability and phase transformation of the ZrSi 2 –B 4 C modified quartz fiber/boron containing phenolic resin (QF/BPR) composite. The compressive failure behavior of the composite at 600–1200 °C was studied through SEM and high-speed camera techniques. The results indicated that the compression strength of the composite decreased to a minimum at 600 °C and increased at 800–1200 °C. The composite exhibited different failure modes at different temperature: shear fracture at room temperature (RT), debonding of the fiber bundles at 600 °C, fiber buckling and fiber shear fracture at 800 °C, fiber buckling and delamination at 1000–1200 °C. The improvement in thermal stability of composite was primarily attributed to the formation of ZrO 2 , SiO 2 and B 2 O 3 , which covered the fiber and effectively transmitted the load, leading to an enhanced strength of the interface between the fiber and resin.
危险品化学品经营许可证（带存储）