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APPLIED RADIATION AND ISOTOPES · 2024 · IF 1.6

Solvents with different moisture levels: Critical impact factors on fluorescence-scintillation properties of liquid scintillators

Yue Li,Yongqiang Zhang,Guoqiang Zhong,Wenjing Pu,Wei Lu,Weihua Wang

Liquid scintillator consists of an organic solvent and one or more scintillation solutes, which can emit light pulses after absorbing X- and γ-rays, or high-energy particles. It has the characteristics of strong neutron/γ-ray (n/γ) discrimination, short decay time, unlimited size and low cost, which plays an important role in high-sensitivity and large-scale radiation detection, especially in the construction and safe operation of nuclear facilities. However, the impact of solvent selection and moisture content on the fluorescence-scintillation properties of scintillators has not been adequately investigated in the literature. In this study, liquid scintillators consisting of scintillation solutes, 2, 5-diphenyl-oxazole and 1, 4-bis (5-phenyl-2-oxazolyl) benzene, were prepared with different moisture contents, which were determined using the Karl-Fischer method. The fluorescence emission spectra, scintillation sensitivity and n/γ discrimination were systematically characterized using various solvents with corresponding moisture contents. The results show that the scintillation count rate and n/γ discrimination reach their maximum values when employing p -xylene as the solvent and maintaining moisture content below 20 ppm. The theoretical calculation elucidates the performance degradation of liquid scintillators induced by moisture.

研究领域: 核物理 · 辐射探测 · 材料科学
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