Efficient detection of aklomide/nitromide based on a sensor of MPA capped CdTe QDs using fluorescence quenching method
Based on the fluorescence sensor of 3-Mercaptopropionic acid (MPA) capped CdTe quantum dots (QDs), two novel detection methods for aklomide and nitromide were developed. The MPA-CdTe QDs were synthesized and characterized by transmission electron microscopy (TEM), thermogravimetric analysis (TGA), X-ray diffraction (XRD), ultraviolet visible (UV–vis) and fluorescence (FL). The quenchings were all static. The binding constants ( K a ) at different temperatures were obtained. Electrostatic forces were the main forces for the two bindings. For the detection of aklomide and nitromide, under the optimal conditions, the effects of some metal ions, glucose, bovine serum albumin (BSA) and congeneric drug on the determination were explored. The standard equations were established and the limits of detection (LOD) were 0.0215 and 0.0388 μg mL −1 (3 S 0 / S ), repectively. The methods were applied to analyse the samples of chicken and duck, the recoveries were 99.41 % – 101.24 % with RSDs of 0.29 % – 1.19 % ( n = 5).
危险品化学品经营许可证（带存储）