Pengyin Deng,Wei Wang,Xiqing Liu,Liang Wang,Yongsheng Yan
The detection of o-nitrophenol in the environment is of great significance to environmental protection. In this paper, the fluorescence sensor of CsPbBr3@SHFW was synthesized by an ultrasonic assisted method using perovskite quantum dots as the fluorescence source and a super hydrophobic porous organic polymer framework (SHFW) as the protective layer. Then CsPbBr3@SHFW was used to detect o-nitrophenol in dichloromethane. Under the optimum conditions, the detection limit of CsPbBr3@SHFW was 7.69 × 10−3 μM, and the linear range was 0–280 μM. It was also proved that the fluorescence quenching of this work is electron transfer. This work provided help for the construction of a stable perovskite quantum dot sensor and the application of a perovskite quantum dot sensor in the field of fluorescence detection.
Covalent organic frameworks (COFs) have attracted tremendous interest due to their promising applications, including electrocatalysis originating from their unique structural features. However, it remains a challenge to prepare COFs for p-nitrophenol (PNP) and o-nitrophenol (ONP) electrocatalysis because it is quite difficult to manipulate their dimension, composition , and morphology with abundant active sites. Here, a facile ambient temperature synthesis of unique Fe 3 O 4 -based magnetic COFs nanosphere (Fe 3 O 4 @AT-COFs) with different surface morphologic structure is reported, which exhibits higher surface area, good water dispersity, long-term stability, excellent electrical conductivity and pre-concentration effect. The prepared Fe 3 O 4 @AT-COF-based electrochemical sensor is then directly employed for the simultaneous detection of PNP and ONP with a wide linear detection range of 10–3000 μM and low detection limits (LOD) of 0.2361 μM and 0.6568 μM, respectively. Meanwhile, the Fe 3 O 4 @AT-COF can be also well-applied in lake and tap water for monitoring PNP and ONP with outstanding sensitivity and reliability, which is expect to be a high-efficient electrocatalyst with great promise for signal amplification of electrochemical sensing.
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