The development of a proton exchange membrane (PEM) that can avoid rapid decay of proton conductivity under low humidity is of great significance for the practical application of PEMFC. In this study, acid–base core–shell microspheres (PCSMs-MA@TAC) with a carboxylic acid core and a triazine shell were synthesized by distillation-precipitation polymerization using cross-linked carboxylic acid microspheres (PMAA) as seeds. These PCSMs were then incorporated into a sulfonated poly(ether ether ketone) matrix to make hybrid membranes. Incorporation of PCSMs microspheres can not only strengthen the vehicle mechanism by increasing the water uptake of the membrane, but also the acid–base pairs formed at the SPEEK/PCSMs interface provide a new low-energy barrier pathway for proton hopping, thereby enhancing the proton conduction of the Grotthuss mechanism. The results show that when the content is 10 wt%, the proton conductivity of the SPEEK/PCSMs-MA@TAC composite membrane can reach 0.161 S cm−1 at 80°C and 100% RH, which is 19.3% higher than the SPEEK control membrane (0.135 S cm−1). In particular, even at 60% RH, the proton conductivity of the SPEEK/PCSMs-MA@TAC-10 composite membrane is still 67 mS cm−1, which is 3.16 times higher than that of the SPEEK membrane. Therefore, the SPEEK/PCSMs-MA@TAC composite membrane can maintain superior performance even under high temperature and low humidity conditions.
Nafion–boron nitride (NBN) nanocomposites with a Nafion-functionalized periphery are prepared via a convenient and ecofriendly Nafion-assisted water-phase exfoliation method. Nafion and the boron nitride nanosheet present strong interactions in the NBN nanocomposite. Then the NBN nanocomposites were blended with Nafion to prepare NBN Nafion composite proton exchange membranes (PEMs). NBN nanocomposites show good dispersibility and have a noticeable impact on the aggregation structure of the Nafion matrix. Connected long-range ionic nanochannels containing exaggerated (−SO3–)n ionic clusters are constructed during the membrane-forming process via the hydrophilic and H-bonding interactions between NBN nanocomposites and Nafion matrix. The addition of NBN nanocomposites with sulfonic groups also provides additional proton transportation spots and enhances the water uptake of the composite PEMs. The proton conductivity of the NBN Nafion composite PEMs is significantly increased under various conditions relative to that of recast Nafion. At 80 °C–95% relative humidity, the proton conductivity of 0.5 NBN Nafion is 0.33 S·cm–1, 6 times that of recast Nafion under the same conditions.
危险品化学品经营许可证（带存储）