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二氯双[二叔丁基-(4-二甲基氨基苯基)膦]钯(II)

规格或纯度: 98% metals basis
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货号 (SKU) 包装规格 是否现货 价格 数量
B294172-250mg
 250mg 现货 Stock Image
B294172-1g
 1g 现货 Stock Image
B294172-5g
 5g 现货 Stock Image
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main product photo

基本描述

别名 Umicore CX84|二氯二叔丁基-(4-二甲基氨基苯基)磷钯(II)
英文别名 887919-35-9|Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)|Pd(amphos)Cl2|(A-taPhos)2PdCl2|PDCL2(AMPHOS)2|MFCD09265123|4-ditert-butylphosphanyl-N,N-dimethylaniline;dichloropalladium|bis(di-tert-butyl(4-dimethylaminophenyl)phosphine
规格或纯度 98% metals basis
英文名称 Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II)
储存温度 充氩
运输条件 常规运输
产品介绍

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.

Application

Bis(di-tert-butyl(4-dimethylaminophenyl)phosphine)dichloropalladium(II) is a highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling with aryl halides including 5- and 6-membered heteroaryl chlorides.
A highly active, air-stable catalyst for Suzuki-Miyaura cross-coupling


Product class

M-P, Homogeneous Catalysts, Monodentate Ligands, Phosphorus Ligands - Achiral


Reaction type

Cross Coupling Reactions with Arenes, Suzuki-Miyaura Coupling Reaction


Chemical properties

Chemical formula

C32H56N2Cl2P2Pd

Empirical formula

[Pd(amphos)2Cl2]

Molecular weight

708.08

Metal

Pd

Theoretical metal content

15

Physical state

powder

Color

yellow

Metal purity

99.95

Applications & references

Synthesis of the pyrazolopyridinone-based p38 mitogen-activated protein kinase inhibitor including a Suzuki coupling reaction. p38 MAP kinases are intercellular serine/threonine kinases which certainly regulate the production and action of several pro-inflammatory mediators. They are also involved in disease states such as rheumatoid arthritis, Crohn’s diseases and psoriasis.


Reference: Org. Proc. Res. Dev. 2011, 15, 31. (DOI: 10.1021/op100205s)

名称和标识符

PubChem SID 488197673
IUPAC Name 4-ditert-butylphosphanyl-N,N-dimethylaniline;dichloropalladium
INCHI InChI=1S/2C16H28NP.2ClH.Pd/c2*1-15(2,3)18(16(4,5)6)14-11-9-13(10-12-14)17(7)8;;;/h2*9-12H,1-8H3;2*1H;/q;;;;+2/p-2
InChi Key DWOZNANUEDYIOF-UHFFFAOYSA-L
Canonical SMILES CC(C)(C)P(C1=CC=C(C=C1)N(C)C)C(C)(C)C.CC(C)(C)P(C1=CC=C(C=C1)N(C)C)C(C)(C)C.Cl[Pd]Cl
Isomeric SMILES CC(C)(C)P(C1=CC=C(C=C1)N(C)C)C(C)(C)C.CC(C)(C)P(C1=CC=C(C=C1)N(C)C)C(C)(C)C.Cl[Pd]Cl
WGK Germany 3
PubChem CID 11714597
分子量 708.07

安全和危险性（GHS）

象形图
ghs07

Harmful
信号词 Warning
危险声明 H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
预防措施声明 P261,P305+P351+P338,P280,P302+P352,P321,P405,P501,P264,P271,P304+P340,P403+P233,P362+P364,P264+P265,P337+P317,P332+P317,P319
WGK Germany 3
个人防护装备 dust mask type N95 (US), Eyeshields, Gloves

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可替换产品

  1. 二氯双[二叔丁基-(4-二甲基氨基苯基)膦]钯(II)
    二氯双[二叔丁基-(4-二甲基氨基苯基)膦]钯(II), 95%, 250mg

    ¥99.90

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