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C-H活化催化剂
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二氯(二甲基乙二肟)(二甲基乙二肟)钴(III)CAS号 : 23638-66-6分子式: C8H15Cl2CoN4O4 分子量: 361.07IUPAC Name: cobalt(3+);(NE)-N-[(3E)-3-hydroxyiminobutan-2-ylidene]hydroxylamine;(NE)-N-[(3E)-3-oxidoiminobutan-2-ylidene]hydroxylamine;dichlorideSMILES: CC(=NO)C(=NO)C.CC(=NO)C(=N[O-])C.[Cl-].[Cl-].[Co+3]InChIKey: HQQCOIVWMUZHKU-KMGPWXGDSA-KInChI: InChI=1S/2C4H8N2O2.2ClH.Co/c2*1-3(5-7)4(2)6-8;;;/h2*7-8H,1-2H3;2*1H;/q;;;;+3/p-3/b2*5-3+,6-4+;;;
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四[N-四氯邻苯二甲酰基-(R)-叔亮氨酸基]二铑双(乙酸乙酯)加合物CAS号 : 2001054-66-4 Compound CID : 146012720分子式: C56H40Cl16N4O16Rh2•C8H16O4 分子量: 1974.17IUPAC Name: 3,3-dimethyl-2-(4,5,6,7-tetrachloro-1,3-dioxoisoindol-2-yl)butanoate;ethyl acetate;rhodium(2+)SMILES: CCOC(=O)C.CCOC(=O)C.CC(C)(C)C(C(=O)[O-])N1C(=O)C2=C(C1=O)C(=C(C(=C2Cl)Cl)Cl)Cl.CC(C)(C)C(C(=O)[O-])N1C(=O)C2=C(C1=O)C(=C(C(=C2Cl)Cl)Cl)Cl.CC(C)(C)C(C(=O)[O-])N1C(=O)C2=C(C1=O)C(=C(C(=C2Cl)Cl)Cl)Cl.CC(C)(C)C(C(=O)[O-])N1C(=O)C2=C(C1=O)C(=C(C(=C2Cl)Cl)Cl)Cl.[Rh+2].[Rh+2]InChIKey: GJJWKGUDHSMMRL-UHFFFAOYSA-JInChI: InChI=1S/4C14H11Cl4NO4.2C4H8O2.2Rh/c4*1-14(2,3)10(13(22)23)19-11(20)4-5(12(19)21)7(16)9(18)8(17)6(4)15;2*1-3-6-4(2)5;;/h4*10H,1-3H3,(H,22,23);2*3H2,1-2H3;;/q;;;;;;2*+2/p-4
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双(1,10-菲罗啉)钯(II)双(六氟磷酸盐)CAS号 : 113173-22-1 Compound CID : 46192367分子式: C24H16F12N4P2Pd 分子量: 756.77IUPAC Name: palladium(2+);1,10-phenanthroline;dihexafluorophosphateSMILES: C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.C1=CC2=C(C3=C(C=CC=N3)C=C2)N=C1.F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.[Pd+2]InChIKey: SPRLLEYDPGIKKF-UHFFFAOYSA-NInChI: InChI=1S/2C12H8N2.2F6P.Pd/c2*1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;2*1-7(2,3,4,5)6;/h2*1-8H;;;/q;;2*-1;+2
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1,3-双(2,6-二异丙基苯基)咪唑鎓-2-羧酸盐CAS号 : 917604-39-8分子式: C28H36N2O2 分子量: 432.61IUPAC Name: 1,3-bis[2,6-di(propan-2-yl)phenyl]imidazol-1-ium-2-carboxylateSMILES: CC(C)C1=C(C(=CC=C1)C(C)C)N2C=C[N+](=C2C(=O)[O-])C3=C(C=CC=C3C(C)C)C(C)CInChIKey: YJFHWSQOLOIECF-UHFFFAOYSA-NInChI: InChI=1S/C28H36N2O2/c1-17(2)21-11-9-12-22(18(3)4)25(21)29-15-16-30(27(29)28(31)32)26-23(19(5)6)13-10-14-24(26)20(7)8/h9-20H,1-8H3
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氯双(二甲基乙二肟)吡啶钴(III)CAS号 : 23295-32-1 Compound CID : 135539555分子式: C₁₃H₁₉ClCoN₅O₄ 分子量: 403.71IUPAC Name: chlorocobalt(1+);(NE)-N-[(3E)-3-hydroxyiminobutan-2-ylidene]hydroxylamine;piperidin-1-ideSMILES: CC(=NO)C(=NO)C.CC(=NO)C(=NO)C.C1CC[N-]CC1.Cl[Co+]InChIKey: HMXQEQFAVFPUEP-DVTASQICSA-MInChI: InChI=1S/C5H10N.2C4H8N2O2.ClH.Co/c1-2-4-6-5-3-1;2*1-3(5-7)4(2)6-8;;/h1-5H2;2*7-8H,1-2H3;1H;/q-1;;;;+2/p-1/b;2*5-3+,6-4+;;
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氯双(二甲基乙二肟)[4-(二甲基氨基)吡啶]钴(III)CAS号 : 483979-48-2分子式: C15H24ClCoN6O4 分子量: 446.78IUPAC Name: cobalt(3+);N,N-dimethylpyridin-4-amine;(NE)-N-[(3E)-3-oxidoiminobutan-2-ylidene]hydroxylamine;chlorideSMILES: CC(=NO)C(=N[O-])C.CC(=NO)C(=N[O-])C.CN(C)C1=CC=NC=C1.[Cl-].[Co+3]InChIKey: QPVNANSKHSJOKN-DVTASQICSA-KInChI: InChI=1S/C7H10N2.2C4H8N2O2.ClH.Co/c1-9(2)7-3-5-8-6-4-7;2*1-3(5-7)4(2)6-8;;/h3-6H,1-2H3;2*7-8H,1-2H3;1H;/q;;;;+3/p-3/b;2*5-3+,6-4+;;
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