Fluorinated HDPE containers are plastic containers in the normal manufacturing process of increase of a fluorination process with fluorine, nitrogen gas mixture on the device in a particular blow molding. After fluorinated HDPE (high density polyethylene) than non-treated container inner wall with a layer of multi-PTFE (polytetrafluoroethylene) as the main material, the fluorinated layer can effectively prevent cracking and pierce the sidewall and an organic solvent penetration and degradation of product, while the PE spacer pads, but also through the fluorination process, more resistant to corrosion, more flexible, no leakage.、