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Dicumyl Peroxide (DCP)


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A cascade reaction, catalyzed by copper, results in the formation of quinazolinone through a radical methylation, sp3 C-H amination, and oxidation process. In this reaction, dicumyl peroxide serves dual functions: as an oxidant and as an effective source of methyl groups.
Y. Bao, Y. Yan, K. Xu, J. Su, Z. Zha, Z. Wang, J. Org. Chem., 2015, 80, 4736-4742.

https://doi.org/10.1021/acs.joc.5b00191


A rhodium-catalyzed carbonylative annulation process effectively produces thiochromenones through a [3+2+1]-type annulation reaction, using nonactivated aromatic sulfides and terminal alkynes as the starting materials.
F. Zhu, X.-F. Wu, J. Org. Chem., 2018, 83, 13612-13617.

https://doi.org/10.1021/acs.joc.8b02294


Quoted 

from:https://www.organic-chemistry.org/chemicals/oxidations/dicumyl-peroxide-dcp.shtm



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Da — 若无特别说明,分子量单位默认为道尔顿。   Mw — 重均分子量。   Mn — 数均分子量。

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阿拉丁科学.《Dicumyl Peroxide (DCP)》. 阿拉丁知识库,更新于 2024年11月28日。 https://www.aladdin-e.com/zh_cn/faqs/dicumyl-peroxide-dcp-en.html
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