技术文章

N-tert-butylbenzenesulfinimidoyl chloride


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A range of unsymmetrical ketones has been prepared in good yields from aldehydes in one simple synthetic operation by addition of organolithium compounds followed by an oxidation using N-tert-butylphenylsulfinimidoyl chloride.
J. J. Crawford, K. W. Hederson, W. J. Kerr, Org. Lett., 2006, 8, 5073-5076.

https://doi.org/10.1021/ol061903l


A one-pot procedure enables the conversion of various ketones into α,β-unsaturated ketones in very good yields under mild conditions via treatment of lithium enolates with N-tert-butyl phenylsulfinimidoyl chloride.
T. Mukaiyama, J.-i. Matsuo, H. Kitagawa, Chem. Lett., 2000, 1250-1251.

https://doi.org/10.1246/cl.2000.1250


Efficient carbon-carbon bond formation of N-carbobenzyloxy amines with 1,3-dicarbonyl compounds at the α-position of nitrogen was established by a one-pot oxidative Mannich reaction using N-tert-butylbenzenesulfinimidoyl chloride as an oxidant.
J-I. Matsuo, Y. Tanaki, H. Ishibashi, Org. Lett., 2006, 8, 4371-4374.

https://doi.org/10.1021/ol0618095


Quoted 

from:https://www.organic-chemistry.org/chemicals/oxidations/n-tert-butylbenzenesulfinimidoyl-chloride.shtm


 

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Da — 若无特别说明,分子量单位默认为道尔顿。   Mw — 重均分子量。   Mn — 数均分子量。

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阿拉丁科学.《N-tert-butylbenzenesulfinimidoyl chloride》. 阿拉丁知识库,更新于 2024年6月13日。 https://www.aladdin-e.com/zh_cn/faqs/n-tert-butylbenzenesulfinimidoyl-chloride-en.html
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