技术文章

Selenium

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Sandra Forbes

 


Recent Literature


The H2Se (or HSe⁻) generated in situ from
Se/DMF/H2O serves as an active reducing species. This reduction system, utilizing water as a cost-effective, safe, and eco-friendly hydrogen donor, demonstrated high selectivity and excellent activity in reducing α,β-unsaturated ketones and alkynes.

C. An, G. Wu, G.-X. Li, X.-B. Huang, W.X. Gao, J.-C. Ding, Y.-B. Zhou, M.-C. Liu, H.-Y. Wu, Org. Lett., 2018, 20, 5573-5577.

DOI: 10.1021/acs.orglett.8b02244

 


H2Se (or HSe⁻), which is generated in situ through the reaction of
Se/DMF/H2O, functions as a potent reducing agent. In this reduction system, water acts as an affordable, safe, and eco-conscious hydrogen donor, exhibiting remarkable selectivity and commendable activity in the reduction of α,β-unsaturated ketones and alkynes.

C. An, G. Wu, G.-X. Li, X.-B. Huang, W.X. Gao, J.-C. Ding, Y.-B. Zhou, M.-C. Liu, H.-Y. Wu, Org. Lett., 2018, 20, 5573-5577.

DOI: 10.1021/acs.orglett.8b02244


Quoted from:

https://www.organic-chemistry.org/chemicals/reductions/selenium.shtm

 

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目录: 技术文章

Da — 若无特别说明,分子量单位默认为道尔顿。   Mw — 重均分子量。   Mn — 数均分子量。

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阿拉丁科学.《Selenium》. 阿拉丁知识库,更新于 2025年8月1日。 https://www.aladdin-e.com/zh_cn/faqs/selenium-en.html
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