Stereoretentive Decarboxylative Amidation with Dioxazolones: A Two-Electron Rearrangement Mechanism for Stereochemical Transfer from Chiral Carboxylic Acids
Many modern decarboxylative coupling reactions employ single-electron processes to generate carbon-centered radicals, followed by subsequent bond formation. For chiral carboxylic acids, however, such pathways present a stereochemical problem: many common carbon-centered radicals are nearly ...
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