Regio- and Stereoselectivity in Monolignol Oxidative Coupling: Single-Electron Oxidation, Radical Coupling, and Dirigent Proteins
Oxidative coupling of monolignols begins with radical formation from phenolic precursors. Coniferyl alcohol is a classical model substrate in studies of lignan oxidative coupling. Its aromatic ring contains a phenolic hydroxyl group at C4 and a methoxy group at C3, while its side chain remains ...
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