Experimental Considerations for the Use of ADMP in the Conversion of Primary Amines to Organic Azides: Substrate Nucleophilicity, Base Matching, and Medium Selection
2-Azido-1,3-dimethylimidazolinium hexafluorophosphate (ADMP) can directly convert primary amines into organic azides under conditions that do not require the addition of an external metal catalyst. Existing studies have shown that this transformation is quite sensitive to substrate type, and ...
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