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In 2014, Tellis, Primer, and Molander reported a photoredox/nickel dual-catalytic cross-coupling involving organotrifluoroborates. Conventional organoboron cross-coupling relies on a two-electron transmetalation process, whereas transmetalation of C(sp³) organoboron reagents is often relatively ...
C(sp2)- and C(sp)-hybridized coupling reactions are established catalytic approaches. However, multi-step C(sp3)- and C(sp2)-coupling reactions of boronic acids and related derivatives are still limited by ineffective two-electron transmetalation reactions. These conventional protocols exhibit ...
Photoredox catalysis has become a powerful synthetic method, which can form Covalent bond under mild reaction conditions through light irradiation.
The photoreaction undergoes a special molecular transformation to form a product that is not obtained through a thermal reaction. In recent years, the light reaction induced by visible light has been further developed. The light reaction in visible light does not require high-energy ultraviolet ...
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