Synthesis of magnetic bentonite–gelatin hydrogel beads and their applications in Cu2+ capturing

Heavy metal ions that exist in groundwater and farmland jeopardize the ecological environment and are very difficult to remove because of the complicated actual environment. Raw bentonite–gelatin beads (RB-GT) and magnetic bentonite–gelatin beads (MB-GT) synthesized in this work would be an appropriate tool to solve this problem. Those beads are synthesized by a facile hybrid injection method. Their adsorption behaviors on Cu(II) ions were systematically investigated using the batch adsorption method. The beads were characterized by scan electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectra (FTIR), and X-ray photoelectron spectroscopy (XPS). The adsorption isotherm and adsorption kinetic study showed that the Cu 2+ adsorption by MB-GT beads fitted the Langmuir model and the pseudo-second model. The adsorption maximum capacities reached 192.5 mg/g and 236.5 mg/g with Cu concentration of 1000 mg/L for RB-GT and MB-GT beads, respectively. The competitive adsorption with other heavy metal ions (Ni(II), Pd(II) and Cd(II)) were compared. The adsorption of Cu(II) mechanisms is also further discussed. Graphical Abstract