Mulch from lignocellulose as agricultural plastic alternative for sustained-release of photosensitive pesticide

Extensively used agricultural mulch fabricated from nonbiodegradable polyolefin plastic causes tremendous environmental pollution. In this work, a paper-based mulch, composed of the cellulose fiber networks incorporated with Emamectin benzoate (EB)@sodium lignosulfonate (SL), has been developed with facile papermaking/coating methods. The spherical microcapsule loaded with pesticide EB has a desirable core-shell structure for better protection and sustained release of photosensitive EB. The loading rate and encapsulation efficiency reached 78.5 % and 52.3 %, respectively. Furthermore, microcapsules exhibited excellent slow-release behavior and resistance to photolysis. Natural carnauba wax was coated on the surface of the paper-based mulch to form a hydrophobic layer and increase the physical intertwinement of fibers in the mulch, thereby exhibiting superior performance, such as enhanced tensile strength , excellent hydrophobicity , high air permeability, and high light transmittance at reasonable level. Moreover, unlike conventional polyethylene mulch film, the functionalized paper-based mulch almost completely biodegraded after 75 days in the soil. Thus, multifunctional, eco-friendly mulch from lignocellulose is an innovative approach to obtaining the sustained release of agrochemicals, and it provides an excellent alternative to conventional agricultural plastic mulch.