New electric field responsive photonic crystals with remarkable yellow-to-green switch for adaptive camouflage

Electric field responsive photonic crystals take on critical significance in developing adaptive camouflage technology, which are promising materials for adaptive camouflage devices with better fabrication processes and color saturation. However, electric field responsive photonic crystals are primarily susceptible to poor fusion with typical background colors and necessitate the continuous implementation of electric fields to attain specific colors, thus limiting their practical applications. Monodisperse polyvinylpyrrolidone modified cadmium sulfide (PVP/CdS) microspheres with large refractive index are well prepared in this study. Liquid photonic crystals, exhibiting earth-yellow and light green under specific electric field, are obtained with PVP/CdS particles dispersed in propylene carbonate in accordance with the subtractive color mixing principle of structural color and initial color. The resulting electric field responsive photonic crystals are characterized by a simple preparation process, fast electrical response, long-time holding of the earth-yellow state, and reversible color changes between earth-yellow and light green in −3.5 V and + 3.5 V electric field switching. This study can contribute to the development of color-changing devices designed for adaptive camouflage applications.