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Thermoelectric properties of Yb-La-Nb-doped SrTiO3

Journal 2023 · IF 5.7 · 发表于 2023 年 10 月 14 日
作者: Lei Zhang,Zheng Cao,Qing-Qiao Fu,Chun-Yu Li,Ya-Qian Du,Yan-Nan Li,Ta La,Dai-Bing Zhang,Jun Wang
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摘要

Yb 2 Ti 2 O 7 exhibits ferromagnetic and magnetic properties , which are expected to exert a discernible influence on the thermoelectric properties of SrTiO 3 composite. The La-Yb-Nb-doped SrTiO 3 powders, synthesized via the hydrothermal method , were prepressed and then buried in carbon powder before being sintered in a muffle furnace at 1573 K for 5 h. The Yb dopant precipitated during the sintering process, leading to the in-situ formation of Yb 2 Ti 2 O 7 . The content of Yb 2 Ti 2 O 7 increased with an increasing Yb concentration, resulting in a reduction in thermal conductivity and grain boundary potentials, and an increase in the peak electrical conductivity . The La and Nb dopants affect the electrical conductivity and the Seebeck coefficient. Therefore, by controlling the La, Nb, and Yb ratios, the La8Yb2Nb15 sample achieved the largest power factor ( PF ) value of 0.9 mWm −1 K −2 and a low thermal conductivity of 2.9 W m −1 K −1 , resulting in a high ZT value of 0.32 at 1000 K.

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