One-Pot Synthesis of Lamellar Fe-Cu Bimetal-Decorated Reduced Graphene Oxide and Its Enhanced Removal of Cr(VI) from Water

Hexavalent chromium (Cr(VI)) is a typical heavy metal pollutant, making its removal from wastewater imperative. Although nanosized zero-valent iron (nZVI) and graphene-based materials are excellent remediation materials, they have drawbacks, such as agglomeration and being difficult to recycle. A facile synthesis method for decorating reduced graphene oxide (rGO) with ultrathin nZVI (within 10 nm) was explored in this study in order to develop an effective tool for Cr(VI) detoxication. Cu particles were doped in these composites for electron-transfer enhancement and were verified to improve the rate by 2.4~3.4 times. Batch experiments were conducted at different pHs, initial concentrations, ionic strengths, and humic acid (HA) concentrations. From these observations, it was found that the acid condition and appearance of Cu and rGO enhanced the treatment capacity. This procedure was fitted with a pseudo-second-order model, and the existence of NaCl and HA impeded it to some extent. Cr(VI) could be detoxified into Cr(III) and precipitated on the surface. Combining these analyses, a kinetics study, and the characterizations before and after the reaction, the removal mechanism of Cr(VI) was further discussed as a complex process involving adsorption, reduction, and precipitation. The maximum removal capacity of 156.25 mg g−1occurred in the acid condition, providing a potential Cr(VI) remediation method.Keywords:nano zero-valent iron (nZVI);reduced graphene oxide (rGO);Cu doping;hexavalent chromium (Cr(VI));removal