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Graphene-like structure of bio-carbon with CoFe Prussian blue derivative composites for enhanced microwave absorption

Journal 2023 · IF 9.9 · 发表于 2023 年 9 月 9 日
作者: Jiahao Wang,Simin Zhang,Zhaolin Liu,Tengge Ning,Junfeng Yan,Kun Dai,Chunxue Zhai,Jiangni Yun
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摘要

Traditional carbon materials such as graphene are often applied in the field of electromagnetic wave (EMW) absorption but they have unbalanced impedance matching and high conductivity. Bio-carbon with graphene-like structure derived from apples has many advantages over graphene: it can be prepared in large quantities and the abundant heteroatoms present in the lattice can provide many polarization phenomena. Herein, Prussian blue analogue (PBA) as a source of magnetic component was combined with bio-carbon or reduced graphene oxide (rGO) to study the EMW absorption properties. The fabricated BC/CFC-12-7 displayed performance with a minimum reflection loss (RL min ) of −72.57 dB and a wide effective absorption bandwidth (EAB) of 5.25 GHz with an ultra-thin and nearly equal matching thickness at 1.61 mm. The results show that the good EMW absorption property of bio-carbon composites comes from good conduction loss, large relaxation polarization loss especially from pyridinic-N, and better impedance matching. The optimized radar cross section is found to be –33.55 dB m 2 in the far-field condition using CST. This work explored the advantages of bio-carbon as a novel EMW absorbing material compared with graphene and provided ideas for realizing high-performance EMW absorbing materials in the future.

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