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Characterization and application of lamellar zeolite-X prepared from kaolin

Journal 2023 · IF 1.3 · 19(1): e12182 · 发表于 2023 年 12 月 20 日
作者: Weilin Jia,Suyang Wang,Yingying Deng,Jie Shen,Ping Zhao,Zepeng Wang,Jiaojing Shao,Yuanyu Wang,Qi Sun
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摘要

A simple and effective method was reported for the rapid synthesis of zeolite X from kaolin by adding a template agent. The results of X-ray diffraction confirm the good crystallinity of the synthesized X-zeolite with lamellar structure. Transmission electron microscopy images clearly demonstrate the lamellar structure of the synthesized X-zeolite. The corresponding selective electron diffraction pattern suggests that the crystal structure of X-type zeolite is octahedral. The co-existence and uniform distribution of Si, Al, O, and Na in the layered structure of the synthesized X-type zeolite are detected by element mapping. In addition, N 2 adsorption–desorption measurement indicates that the specific surface area of the lamellar zeolite X is 153.4625 m 2 g −1 . The micropore surface area is 148.8374 m 2 g −1 , and the micropore volume is 0.073377 m 2 g −1 . After exploring the influence of different temperatures on the adsorption of carbon dioxide, the research shows that two-dimensional zeolite X has the best adsorption capacity for carbon dioxide. The adsorption and separation performance of CO 2 /CH 4 was investigated. The study showed that the adsorption and separation coefficient of two-dimensional zeolite X was the highest.

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