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CO2 capture from flue gas using EAE-1DMA2P solvent in a packed column

Journal 2023 · IF 15.1 · 发表于 2023 年 12 月 7 日
作者: Shuai Wang,Chunliang Shang,Yimin Deng,Jan Baeyens,Tatiana V. Plisko,Alexandr V. Bildyukevich,Tejraj M Aminabhavi,Xinying Liu,Mahluli Moyo,Helei Liu
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摘要

The mass transfer plays a decisive role in screening and evaluation of amine solvents as well as in designing and scale-up of CO 2 capture. The influence of different operating parameters on mass transfer processes in CO 2 capture by EAE-1DMA2P amine solution was thoroughly investigated using a small-scale packed column. The mass transfer mechanism of EAE-1DMA2P amine solution in the capture of CO 2 was discussed by determining both mass transfer control steps and the reaction region between CO 2 and amine solvent, which provided a theoretical guidance for subsequent development of new solvents for large-scale applications. In addition, based on the experimental observations of K G a v KGav , a prediction model for K G a v KGav of EAE-1DMA2P composite amine solution was established by comparing two empirical models viz., Kohl-Riesenfeld-Astarita and Sheng of which Kohl-Riesenfeld-Astarita model provided a better fitting of the experimental results. The commonly used amine solvents and EAE-1DMA2P composite solvents were further compared and analyzed in terms of packed column size design and solvent consumption. The required packed column volume using EAE-1DMA2P composite solvent was only 4.95 m 3 , while the EAE-1DMA2P composite solvent has the smallest solvent consumption among all the solvents, indicating that this solvent has a lower operating cost than the other solvents, suggesting better industrial application.

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