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Bamboo-like tubular nitrogen-doped carbon derived from g-C3N4 as an ultra-high performance anode of potassium-ion battery

Journal 2023 · IF 6.7 · 发表于 2023 年 8 月 25 日
作者: Shasha Wang,Qing Wang,Wuxin Liu,Yuli Wei,Yan Wang,Shaohua Luo,Pengqing Hou,Yahui Zhang,Shengxue Yan,Xin Liu
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摘要

Carbon materials are still the most widely studied anode materials for potassium ion batteries (PIBs) attributed to their advantages of wide source, controllability, and environmental friendliness. In this paper, a bamboo-like tubular nitrogen-doped carbon material (CNC) was prepared by using g-C 3 N 4 as the precursor and transition metal salt as the catalyst and template. CNC has the advantages of a bamboo-like tubular structure, rich nitrogen content, and large layer spacing. As anode of PIBs, CNC can deliver an impressive initial reversible capacity of 488.6 mAh/g at 0.1 A/g. At a high current density of 1 A/g, CNC still retains a reversible capacity of 291 mAh/g after 1000 cycles. The excellent performance of CNC anode can be due to the porous bamboo-like tubular structure that promotes K ions diffusion and the rich nitrogen content that provides abundant active sites for K ions.

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