Treating waste with waste: Adsorption of anionic dyes in wastewater with surfactant-modified phosphogypsum

Phosphogypsum (PG) is a solid waste generated during the wet process of phosphoric acid production. The environmental-friendly disposal and recycling of PG is vital in the field of environmental solid waste treatment . In this study, PG is used for adsorbent of dyes in wastewater to achieve the goal of recycling waste with waste. Surfactant-modified phosphogypsum (ODBAC@PG) was prepared using octadecyl dimethyl benzyl ammonium chloride (ODBAC) as modifier. ODBAC@PG exhibits high adsorption capability for anionic dyes (methyl blue (MeB) and indocyanine carmine (IC)). The pseudo-second-order kinetic model fits the kinetic experimental data for the adsorption of two organic anionic dyes. Langmuir adsorption isotherm fits the adsorption characteristics of MeB and IC on ODBAC@PG, exhibiting a monolayer adsorption pattern. Thermodynamic parameters indicate the spontaneous and exothermic properties of MeB and IC on ODBAC@PG. MeB and IC have antagonistic effects on each other in binary adsorption system. High adsorption capacity after six cycles of experiments demonstrates the high reusability of ODBAC@PG. The nature for the adsorption includes electrostatic interaction, hydrogen bond and hydrophobic interaction. Using ODBAC@PG for dyes wastewater treatment can accomplish the goal of treating waste with waste and turning waste into treasure.