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Gelatin aerogel with good mechanical properties and adjustable physical properties for boron adsorption from salt lake brines: An optimized process

Journal 2023 · IF 8.2 · 发表于 2023 年 8 月 18 日
作者: Tongtong Pan,Xiangmei Cui
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摘要

A composite aerogel with good mechanical properties and adjustable physical properties was synthesized by a sol-gel technique on the base of gelatin for the boron adsorption from water solution. The adsorption key variables, for instance, initial boron concentration (C 0 ) (900–1100 mg/L), the contact time (t) (8–9 h), and pH (9–11), were optimized using central composite design to obtain improved boron adsorption performance of epichlorohydrin-modified gelatin (EMG)/ N -methyl- d -glutamine (NMDG) aerogel loaded with hydroxylated carbon nanotubes (EMG@NMDG). The adsorption followed the pseudo-second-order and Freundlich model. At pH of 10, C 0 of 1000 mg/L and t of 10 h, the largest adsorbed amount of EMG@NMDG was 85.79 mg/g. Regeneration experiments were carried out by eluting the adsorbent using HCl. The analysis showed that the adsorption in actual brine was 62.65 mg/g. Therefore, the developed EMG@NMDG aerogel has potential value for the boron extraction from brine and wastewater.

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