Preparation of spherical porous carbon from lignin-derived phenolic resin and its application in supercapacitor electrodes

Lignin is the most abundant aromatic biomass resource in nature and is the main by-product of paper industry and biorefinery industry, which has the characteristics of abundant source, renewable and low cost. Deep eutectic solvents (DES) are a nascent environmentally friendly solvent option that is gaining traction. DES composed of p -toluenesulfonic acid and choline chloride is used for batch treatment of alkaline lignin, and the bio-oil obtained is ternary polymerized with formaldehyde and phenol to obtain lignin phenolic resin. The porous carbon material is produced through a two-step carbonization process, utilizing phenolic resin derived from lignin as the primary source of carbon. The morphology and composition of the carbon were analyzed by SEM, TEM, XRD, TGA , XPS and Raman spectroscopy , the specific surface area and pore size distribution were analyzed by BET. The results showed that the specific surface area of the lignin-based phenolic resin was significantly higher than that of the pure phenolic resin carbon, and the porous carbon material that was acquired demonstrated a specific surface area of as much as 1026 m 2 /g. In the three-electrode system, the specific capacitance of DLPFC can reach 245.8 F/g (0.25 A/g), with a very small decrease in the value of specific capacitance at 10,000 cycles, with a retention of 97.62% (10 A/g). The porous carbon demonstrated a specific capacitance of 112.4 F/g at a current density of 0.5 A/g, and the capacitance retention rate could still reach 98.8% after 5000 charge/discharge cycles, with high cycling stability (in the two-electrode system). The prepared symmetrical supercapacitors exhibited high energy density and power density of 3.9 Wh/kg and 125.0 W/kg. The results suggest a new idea of high value-added application of lignin phenolic resin for high-performance supercapacitor electrodes.