Boosted nitrilation of dimethyl adipate with NH3 to adiponitrile over bimetallic oxide: Synergetic effect between Nb and W

To reach highly active and selective gas-phase nitrilation of dimethyl adipate (DMA) with NH 3 , a series of Nb x W 10-x (x = 10, 9, 7, 5 and 0) composite were fabricated by a sol–gel method to approach the homogeneous combination of NbO x and WO x . As a result, the single-pass yield of adiponitrile (ADN) reached 85.2% over Nb 9 W 1 under lower reaction temperature and lower NH 3 /DMA molar ratio. Consequently, the space–time yield (STY) of ADN over Nb 9 W 1 was 1.7 ∼ 30 times higher than that of previous catalysts. Mechanistic experiments demonstrated the activity strongly correlates the interaction between the carbonyl functionality and the composite. Further, a significant synergistic effect between W and Nb was disclosed, wherein the Nb-based domains account for activating DMA while the W-based domains mainly adsorb and activate NH 3 feedstock.