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One-step synthesis of novel carbon dots through cross amide formation of benzene-1,3,5-triamine and trimethyl 1,3,5-benzenetricarboxylate for fluorescence Hg2+ detection

Journal 2023 · IF 4.5 · 发表于 2023 年 6 月 16 日
作者: Shaofang Ma,Zihan Zhu,Jianfei Xu,Jing Wang,Xinjing Tang,Wei Bian
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摘要

Herein, we rationally designed and synthesized novel green-emitting fluorescent carbon dots (CDs) through cross amide formation of two precursors, benzene-1,3,5-triamine trihydrochloride and trimethyl 1,3,5-benzenetricarboxylate, under hydrothermal treatment . The average particle size of the CDs was ∼2.7 nm with graphitic carbon structures. The obtained CDs showed good photoluminescent properties with a quantum yield of up to 11.2%. The carbon dots showed good fluorescence sensitivity and selectivity for Hg 2+ , and the LOD and LOQ values were 17.5 pM and 58.3 pM in the range of 0.1–0.8 μM, which could be successfully applied to Hg 2+ detection in real water samples as well as intracellular Hg 2+ fluorescence detection .

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