Aging, characterization and sorption behavior evaluation of tire wear particles for tetracycline in aquatic environment

Accounting for more than half of the total primary microplastic (MP) emissions, and one-sixth of the total marine MP pollution in China in 2015, tire wear particles (TWP) are inevitable to age and interact with co-existing species, thus pose a potential risk to the surroundings. The impacts of simulated ultraviolet radiation weathering and liquid-phase potassium persulfate oxidation of TWP on the surface physicochemical properties were comparatively explored. The characterization results demonstrated that the content of carbon black, particle size and specific surface area of the aged TWP all decreased, while the changes of the hydrophobicity and polarity were inconsistent. The interfacial interactions with tetracycline (TC) in aqueous were investigated, the well fitted pseudo-second-order kinetics, Dual-mode Langmuir and Scatchard isotherm models indicated the attachment of TC dominated by surface adsorption at lower concentration, and there's a positive synergistic effect among the main sorption domains. Moreover, the results of the influences of co-existing salts and natural organic matter revealed that the potential risks of TWP elevated by the adjacent media in natural compartment. This work provides new insights into the way that TWP interact with contaminants in the real environment.