One-step hydrothermal preparation of bi-functional NiS2/reduced graphene oxide composite electrode material for dye-sensitized solar cells and supercapacitors

To screen out suitable electrode materials and overcome the shortcomings of the existed electrode materials for the application in dye-sensitized solar cells and supercapacitors , NiS 2 /reduced graphene oxide (NiS 2 /rGO) composite material was prepared by a simple one-step hydrothermal method in this paper and applied in the field of both dye-sensitized solar cells and supercapacitors as electrode material. In an electrolyte of 6 M KOH, the NiS 2 /rGO composite material with bilayer capacitance characteristics exhibited a high specific capacitance of 259.20 F g −1 at the current density of 0.6 A g −1 , which was significantly higher than that of rGO (188.94 F g −1 ). Moreover, at a current density of 2 A g −1 , the NiS 2 /rGO composite material had 92.85% capacitance retention after 2000 cycles. When applied as counter electrode material for the dye-sensitized solar cells, the NiS 2 /rGO composite material counter electrode exhibited a satisfactory photoelectric conversion efficiency ( η ) of 3.16% under standard simulated sunlight (AM 1.5 G), which was significantly higher than that of single rGO counter electrode (improved by 90.40%). The NiS 2 /rGO composite electrode material prepared by a simple one-step hydrothermal method is a potential bi-functional composite electrode materials for both dye-sensitized solar cells and supercapacitors.