H2O2 modified peanut shell-derived biochar/alginate composite beads as a green adsorbent for removal of Cu(II) from aqueous solution

In this study, a novel composite bead (MPB-ALG) was prepared by encapsulating H 2 O 2 modified peanut shell-derived biochar (MPB) into alginate matrix through a facile method. The structure and properties of prepared materials were characterized using FTIR , BET, SEM, and XPS . Batch adsorption experiments were performed to compare the Cu(II) adsorption performance of MPB, plain alginate beads (ALG), and MPB-ALG. The effect parameters of the components, solution pH, contact time, initial concentration, and coexisting ions were studied systematically. The results showed that the maximum adsorption capacity of the optimized MPB-ALG-1 (MPB/alginate = 1:1 w/w%) was 117.4 mg g −1 at pH 5, which was much higher than that of MPB (37.4 mg g −1 ). The adsorption kinetics and isotherms data of Cu(II) on MPB-ALG-1 were well described by Elovich kinetic model and Freundlich adsorption isotherm. Compared with plain ALG beads, MPB-ALG-1 exhibited better reusability and anti-interference of coexisting ions. Finally, the adsorption mechanisms of Cu(II) on MPB-ALG-1 beads were revealed by FTIR and XPS analysis. The experimental results demonstrated that MPB-ALG-1 beads can be used as an environmentally friendly and efficient adsorbent for the removal of Cu(II) from wastewater.