Influence of pre- or post-electron beam irradiation on heat-moisture treated maize starch for multiscale structure, physicochemical properties and digestibility

Electron beam irradiation (EBI) as a green technological method for starch modification can generate starch-based materials with new functions. This study modified maize starch by heat-moisture treatment (HMT) for 1 h and 3 h, and EBI with various intensities (5 kGy and 10 kGy), and their effects of treatment sequence on the multiscale structure, physicochemical properties and in vitro digestibility were investigated. EBI or HMT alone did not change the granule morphology and crystalline type, but reduced the crystallinity and molecular weight and increased the resistant starch content. HMT alone had no significant effect on the solubility of starch, while EBI led to a considerable increase in the solubility of maize starch. The combined treatment of EBI and HMT aggravated apparent viscosity reduction, and the HMT starch pretreated with EBI had a smaller molecular weight and lower viscosity. In contrast, post-EBI samples had higher solubility and RS content. Primarily, it has excellent potential for producing low-viscosity and high-solubility starch foods .