Green and recyclable graphitic carbon nitride/chitosan/polyvinyl alcohol photocatalytic films with efficient antibacterial activity for fruit packaging

Chitosan (CS) is an excellent raw material for the preparation of food packaging films due to its good film-forming properties, non-toxicity, and biodegradability . However, pure chitosan films have drawbacks such as weak mechanical properties and limited antimicrobial activity . In this work, novel food packaging films containing chitosan, polyvinyl alcohol (PVA) and porous graphitic carbon nitride (g-C 3 N 4 ) were successfully prepared. The PVA served to improve the mechanical properties of the chitosan-based films, whilst the porous g-C 3 N 4 acted as a photocatalytically-active antibacterial agent. The tensile strength (TS) and elongation at break (EAB) of the g-C 3 N 4 /CS/PVA films both increased by ~4 times compared to the pristine CS/PVA films at the optimum g-C 3 N 4 loading of ~10 wt%. The addition of g-C 3 N 4 increase the water contact angle (WCA) of the films from 38° to 50°, whilst decreasing the water vapor permeability (WVP) from 160 × 10 −12 to 135 × 10 −12  g∙Pa −1  s −1  m −1 . The shelf life of strawberries covered with g-C 3 N 4 /CS/PVA films at room temperature could be extended up to 96 h, compared to 48 h and 72 h for strawberries covered with polyethylene (PE) films or CS/PVA films, respectively. The g-C 3 N 4 /CS/PVA films offered good antibacterial properties against Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ). Further, the composite films could be easily recycled with the regenerated films offering almost identical mechanical properties and activities as the original films. The prepared g-C 3 N 4 /CS/PVA films thus offer promise for low-cost antimicrobial packaging applications.