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Platinum Immobilized in Imidazolyl Schiff Base-Containing Nitrogen-Rich Covalent Organic Polymer as a Catalyst for Hydrosilylation

Journal 2023 · IF 0.9 · 93(1): 120-127 · 发表于 2023 年 3 月 9 日
作者: Huo Y. P.,Liu F.,Wu J. P.,Zhang Y. K.,Feng C. M.,Peng Y.
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摘要

Abstract An imidazolyl Schiff base containing nitrogen-rich covalent organic polymer (COP) was synthesized via polycondensation reactions between bis(imidazolyl)imine-bridged bis silane and melamine under solvent thermal condition. The as-synthesized COP was then employed as a solid support for platinum catalyst. This heterogeneous catalyst was fully characterized via technics including FTIR, solid-state 13 C NMR, X-ray photoelectron spectroscopy (XPS), as well as N 2 absorption/desorption analysis, X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) methods. The catalyst was efficient in mediating hydrosilylation reactions between olefins and triethoxylsilane.

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