Synthesis and coloring properties of novel stablized green Ni0.15MgxAl2(0.85-x)Ti1.15+xO5 pigments

Novel stablized green Ni 0.15 Mg x Al 2(0.85- x ) Ti 1.15+ x O 5 (0 ≤  x  ≤ 0.25) pigments were prepared by solid-state method using Ni 2 O 3 as colorant and Mg(CH 3 COO) 2 ‧4H 2 O as auxiliary stabilizer . The synthesised pigments were characterized via XRD , XPS , SEM, TEM, UV-Vis, and automatic colorimeters. The results show that Mg-doping increases the oxygen vacancies , resulting in a positive shift of the binding energy of Ni 2+ irons. The formation of Ni 0.15 Mg x Al 2(0.85- x ) Ti 1.15+ x O 5 solid solution greatly increases the energy transfer energy and shifts the emission to lower wavelengths (530 nm), corresponding to the visible diffuse reflection of green light. The chromaticity of the pigment changed little ( L* =72.51, a* =−18.16, b* =20.94) at 1200 ℃ for 10 h, showing excellent thermal stability. The properties especially excellent thermal stability makes it promising novel green pigments in ceramic industry application.