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Bifunctional collagen fiber/carbon quantum dot fluorescent adsorbent for efficient adsorption and detection of Pb2+

Journal 2023 · IF 9.8 · 发表于 2023 年 2 月 6 日
作者: Limin Jing,Qijun Ding,Xia Li,Jiang Lou,Zhuqing Liu,Yifei Jiang,Wenjia Han,Zheng Cheng
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摘要

In this work, fluorescent adsorbents that can efficiently detect and remove Pb 2+ were developed by integrating the designed amino-modified carbon quantum dots and carboxyl-modified collagen. The adsorption properties of the fluorescent adsorbent were further optimized and analyzed using a series of response surface experiments. The maximum adsorption concentration for Pb 2+ was 183 mg.g −1 . The adsorption isotherms fit well with the Langmuir model, and the adsorption kinetics fit with the pseudo-second-order model. The emission intensity of the fluorescent adsorbent gradually decreased with the increase of the concentration of Pb 2+ , and had a good linear correlation. In addition, the mechanism of detection and removal of Pb 2+ by fluorescent adsorbents was further demonstrated. The novel three-dimensional structured fluorescent aerogel can be used as a promising adsorbent with good adsorption concentration and sensing ability for Pb 2+ , which shows great prospects in wastewater.

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