Transformation of silver nanospheres into triangular nanoplates through a photoinduced process

Triangular silver nanoplates exhibit excellent optical and catalytic properties in many fields, such as catalysts, sensors and bio-medicine. In this paper, triangular nanoplates were generated just in the presence of sodium citrate through a light-induced ripening process, which were converted from spherical silver nanoparticles by reducing silver nitrate with sodium borohydride. By using UV–Vis spectroscopy, particle size analyzer, transmission electron microscopy (TEM) and Ag + concentration analysis, the effects of precursors during the preparation of triangular nanoplates were systematically investigated and the optimal experimental conditions were determined. Based on density functional theory (DFT), the adsorption energies of citrate ion, malate ion and tartronate ion on Ag (1   1   1), (1   1   0) and (1   0   0) were calculated. In addition, theoretical calculations coupled with experimental observations showed that citrate ion as capping agent could more preferentially bind to Ag (1   1   1) and thus blocked Ag (1   1   1) while only allowing extensive growth along the lateral direction. This well explains sodium citrate is an efficient agent in preparing triangular silver nanoplates.